黃正良 教授
一、學歷:
國立清華大學化學博士 (2000)
國立清華大學化學碩士 (1996)
國立清華大學化學學士 (1994)
二、經歷:
2000-2003 中央研究院博士後研究員
2003-2011 嘉義大學應用化學系暨研究所助理教授
2011- 2016 嘉義大學應用化學系暨研究所副教授
2016-現在 嘉義大學應用化學系暨研究所教授
三、專業領域:
物理化學
四、連絡方式( Tel or e-mail):
05-271 7963
clhuang@mail.ncyu.edu.tw
五、研究方向:
目前主要的研究方向是以光化學方法合成不需覆蓋試劑(capping agent)的奈米粒子以及拉曼光譜研究。近幾年來奈米科技的快速發展,使奈米粒子被廣泛的應用於催化、生物與化學感測器、光電子元件及表面增強拉曼光譜(SERS)的激發基質等方面。如此廣泛的應用主要是奈米粒子異於塊材(bulk)的種種性質。而不含覆蓋試劑的奈米粒子更可以凸顯出奈米粒子其優異的表面性質。利用光化學合成法,則讓我們可以較精準地控制實驗條件。
在未來的研究會朝奈米粒子的合成及其應用與表面增強拉曼光譜發展。在奈米粒子研究上,除了發展新型態的奈米粒子合成之外,還有改變實驗條件來探討奈米粒子的生成及其性質。並且利用奈米粒子的特殊性質來做生物檢測與表面增強拉曼光譜。
![](https://ncyuweb.ncyu.edu.tw/files/site_content/chem/gg.jpg)
在不同時間下終止蝕刻反應所得各種的奈米銀溶液顏色與其消光光譜對應圖
六、期刊著作:校務系統研究成果
1. Gen-Hou Leu, Cheng-Liang Huang , Shih-Huang Lee, Yu-Chang Lee, and I-Chia Chen, “Vibrational levels of the transition state and rate of dissociation of triplet acetaldehyde”, J. Chem. Phys. 109 , 9340 (1998) (SCI)
2. Cheng-Liang Huang , Volume Chien, Chi-Kung Ni, A. H. Kung, and I-Chia Chen, “State-resolved dissociation dynamics of triplet acetaldehyde near the dissociation threshold to form CH 3 +HCO”, J. Chem. Phys. 112 , 1797 (2000) (SCI)
3. Cheng-Liang Huang , Shan-Shan Ju, Anthony J. Merer, Chi-Kung Ni, A. H. Kung, and I-Chia Chen, “High-Resolution Spectroscopy of Jet-Cooled 32 SO 2 and 34 SO 2 ; the 3 B 1 - 1 A 1 , and bands”, J. Mol. Spectros. 203 , 151 (2000) (SCI)
4. Cheng-Liang Huang , Volume Chien, Chi-Kung Ni, A. H. Kung, and I-Chia Chen, “State-Resolved Dynamics of Dissociation of Triplet Acetaldehyde: Rate of Appearance of Fragment HCO and Decay of Excited State of Parent Molecule”, J. Phys. Chem. A. 104 , 10362 (2000). (SCI)
5. Cheng-Liang Huang , Anthony J. Mere, Chi-Kung Ni, A. H. Kung, and I-Chia Chen, “Spectra of jet-cooled 32 SO 2 and 34 SO 2 in systems 3 B 1 and 3 A 2 - 1 A 1 : rotational structure of perturbed 3 A 2 ” , J. Chem. Phys. 114 , 1187 (2001) . (SCI)
6. Shang-Ting Tsai, Cheng-Liang Huang , Yuan. T. Lee, and Chi-Kung Ni, “Ring opening dissociation of d6-benzene” J. Chem. Phys. 115 , 2449 (2001). (SCI)
7. Yung-Ching Chou, Cheng-Liang Huang , Chi-Kung Ni, A. H. Kung, and I-Chia Chen, “Rotational resolved spectra of transitions involving motion of the methyl group of acetaldehude in the system ”, J. Chem. Phys. 115 , 5089 (2001). (SCI)
8. Yung-Ching Chou, Cheng-Liang Huang , Chi-Kung Ni, A. H. Kung, and I-Chia Chen, “Rotational resolved spectra of transition involving methyl torsion and C-C-O bend of acetaldehyde in the system ”, J. Chem. Phys. 116 , 1003 (2002). (SCI)
9. C . H. Chang, Cheng-Liang Huang , Chi-Kung Ni, H. L. Dai, M. Hayashi, K. K. Liang, A. H. Kung, I-Chia Chen, and S. H. Lin, “Experimental and Theoretical Studies of the Effect of Collision and Magnetic Field on Quantum Beat” Mol. Phys, 100 , 1117 (2002). (SCI)
10. Cheng-Liang Huang , Jyh-chiang Jiang, Sheng Hsien Lin, Yuan T. Lee, and Chi-Kung Ni, “Photodissociation and photoisomerization of small aromatic molecules in a molecular beam”, Aust. J. Chem., 54 , 561-571 (2001) (SCI)
11. Cheng-Liang Huang , Jyh-chiang Jiang, Sheng Hsien Lin, Yuan T. Lee, and Chi-Kung Ni, “Photodissociation of ethylbenzene at 248 nm”, J. Chem. Phys. 116 , 7779 (2002). (SCI)
12. Chih-Kai Lin, Cheng-Liang Huang , Jyh-chiang Jiang, A. H. H. Chang, Yuan T. Lee, Sheng Hsien Lin, and Chi-Kung Ni, “photodisomerization and photodissociation of toluene in molecular beam” J. Am. Chem. Soc. 124 , 4068-4075 (2002). (SCI)
13. Yung-Ching Chou, Cheng-Liang Huang , Chi-Kung Ni, A. H. Kung, and I-Chia Chen, “ Rotationally resolved structures in the fifth and sixth torsional states of acetaldehyde: Internal rotation above the torsional barrier ”, J. Chem. Phys. 117 , 4906 (2002). (SCI)
14. Cheng-Liang Huang , Hon-Huei Liu, T. Lin Liu, A.H. Kung, and Chi-Kung Ni, “Rotationally resolved laser induced fluorescence of biacetyl in ” J. Chem. Phys 117 , 5165 (2002). (SCI)
15. Cheng-Liang Huang , Jyh-chiang Jiang, A. H. H. Chang, Yuan T. Lee, Sheng Hsien Lin, and Chi-Kung Ni, “Photodissociation of ethylbenzene and n-propylbenzene in a molecular beam” J. Chem. Phys 117 , 7034 (2002). (SCI)
16. Huang, C.-L.; Jiang, J.-C.; Lee, Y. T.; Ni, C.-K , “ Photoisomerization and Photodissociation of m -Xylene in a Molecular Beam “ J. Phys. Chem. A. 107 , 4019 (2003). (SCI)
17. Ming-Fu Lin, Cheng-Liang Huang , Yuan T. Lee, and Chi-Kung Ni , “ Photodissociation dynamics of azulene “J. Chem. Phys 119 , 2032 (2003). (SCI)
18. Huang, C.-L. ; Jiang, J.-C.; Mebel, A. M.; Lee, Y. T.; Ni, C.-K. “ Photodissociation Dynamics of Fluorobenzene “ J. Am. Chem. Soc. 125 , 9814 (2003). (SCI)
19. Ming-Fu Lin, Cheng-Liang Huang , Vadium V. Kislov, A. M. Mebel, Yuan T. Lee, and Chi-Kung Ni. “H and CH 3 elimination in the photodissociation of chlorotoluene.” J. Chem. Phys 119 , 7701 (2003). (SCI)
20. Tseng, C.-M.; Choi, Y. M.; Huang, C.-L .; Ni, C.-K.; Lee, Y. T.; Lin, M. C. “Photodissociation of Nitrosobenzene and Decomposition of Phenyl Radical” J. Phys. Chem. A. 108 , 7928 (2004) (SCI)
21. Tseng, C.-M.; Dyakov, Y. A.; Huang, C.-L .; Mebel, A. M.; Lin, S. H.; Lee, Y. T.; Ni, C.-K.” Photoisomerization and Photodissociation of Aniline and 4-Methylpyridine” J. Am. Chem. Soc.; 126, 8760-8768 (2004) (SCI)
22. Cheng-Liang Huang, Yuri A. Dyakov, S. H. Lin, Yuan T. Lee, and Chi-Kung Ni “Photodissociation Dynamics of Ethyltoluene and p-Fluoroethylbenzene at 193 and 248 nm” J. Phys. Chem. A 109 , 4995 (2005) (SCI)
23. Cheng-Liang Huang a, Chen-Lin Liu b, Chi-Kung Ni b, Jon T. Hougen, “ Electronic spectra of molecular with two C 3v internal rotors: Torsional analysis of the LIF spectrum of biacetyl” J. Mol. Spectros. 233 , 122 (2005) (SCI)
24. Hsu-Chen Hsu, Jia-Jia Lyu, Chen-Lin Liu, Cheng-Liang Huang and Chi-Kung Ni “ Generation and characterization of highly vibrationally excited molecular beam” J. Chem. Phys. 124 , 054301 (2006)
25. Cheng-Liang Huang, Jyh-Chiang Jiang, Yuri A. Dyakov, Ming-Fu Lin, Chien-Ming Tseng, S. H. Lin, Yuan “Photodissociation and photoisomerization of α-fluorotoluene and 4-fluorotoluene in a molecular beam” J. Chem. Phys. 125 , 133305 (2006)
26. Chien-Ming Tseng , Yuri A. Dyakov, Cheng-Liang Huang, Yuan T. Lee, Sheng-Hsien Lin and Chi-Kung Ni “The Role of Seven-membered Ring in the Photoisomerization and Photodissociation of Small Aromatic Molecules” Journal of the Chinese Chemical Society. 53 , 33-40 (2006)
27. Shih-Hong Ciou, Yi-Wei Cao, Huai-Cing Huang, De-Yan Su, and Cheng-Liang Huang “SERS Enhancement Factors Studies of Silver Nanoprism and Spherical Nanoparticle Colloids in The Presence of Bromide Ions” J. Phys. Chem. C. 113 , 1501-1507 (2009)
28. Kun-Yu Lin, Chia-Teh Su, Ling-Jiun Wang, Cheng-Liang Huang, Mong Liang “New Manganese Catalyzed Regiocontrolled Synthesis of Poly(2,5-dialkyl-1,4-phenylene oxide)s” J. Appl. Polym. Sci. 111 , 1501-1507 (2009)
29. Cheng-Liang Huang , Wei-Chun Cheng, Jia-Ci Yang, Meng-Chun Chi, Jiau-Hua Chen, Hong-Ping Lin, Long-L “Preparation of carboxylated magnetic particles for the efficient immobilization of C-terminally lysine-tagged Bacillus stearothermophilus aminopeptidase II” Ind Microbiol Biotechnol. 37 , 717-725 (2010)
30. Yao-Chang Lee, Sin-Jia Chen and Cheng-Liang Huang “Finding a Facile Method to Synthesize Decahedral Silver Nanoparticles through a Systematic Study of Temperature Effect on Photomediated Silver Nanostructure Growth” Journal of the Chinese Chemical Society. 57 , 325-337 (2010)
31. Bo-Hong Lee, Ming-Sheng Hsu, Yuan-Chin Hsu, Cheng-Wei Lo, and Cheng-Liang Huang “A Facile Method To Obtain Highly Stable Silver Nanoplate Colloids with Desired Surface lasmon Resonance Wavelengths” J. Phys. Chem. C. 114, 6222-6227 (2010)
32. Ming-Sheng Hsu, Yi-Wei Cao, Hsuang-Wen Wang, Ya-Sin Pan, Bo-Hong Lee, and Cheng-Liang Huang “Time-Dependent Surface Plasmon Resonance Spectroscopy of Silver Nanoprisms in the Presence of Halide Ions” ChemPhysChem. 11, 1742-1748(2010)
33. Yu-Min Huang, Szu-Hsueh Lai, Sheng Jui Lee, I-Chia Chen, Cheng-Liang Huang, Shie-Ming Peng, and Wen- “Metal Metal Bonding and Structures of Metal String Complexes Tripyridyldiamido Pentanickel and Pentacobalt from IR, Raman, and Surface-Enhanced Raman Scattering Spectra” J. Phys. Chem. C. 115, 2454-2461 (2011)
34. Yu-Min Huang, Huei-Ru Tsai, Szu-Hsueh Lai, Sheng Jui Lee, I-Chia Chen*, Cheng-Liang Huang, Shie-Ming “Bonding between Chromium Atoms in Metal-String Complexes from Raman Spectra and Surface-Enhanced Raman Scattering Vibrational Frequency of the Chromium Quadruple Bond” J. Phys. Chem. C. 115, 13919-13926 (2011)
35. Li-Chen Yang, Yen-Shang Lai, Chin-Ming Tsai, Yi-Ting Kong, Cheng-I Lee,* and Cheng-Liang Huang* “One-Pot Synthesis of Monodispersed Silver Nanodecahedra with Optimal SERS Activities Using Seedless Photo-Assisted Citrate Reduction Method” The Journal of Physical Chemistry C. 116, 24292-24300 (2012)
36. Chin-Ming Tsai, Ming-Sheng Hsu, Jui-Chang Chen*, and Cheng-Liang Huang“Mechanistic Study of Shape Evolution of Silver Nanoprisms in The Presence of KSCN” J. Phys. Chem. C. 116, 461-467(2012)
37. Shi-Min Shau, Tzong-Yuan Juang, Han-Sheng Lin, Cheng-Liang Huang, Chi-Fa Hsieh, Jeng-Yue Wu, Ru-Jon “Individual graphene oxide platelets through direct molecular exfoliation with globular amphiphilic hyperbranched polymers” Polym. Chem.. 3, 1249-1259 (2012)
38. Yi-Hsin Chien, Ming-Fong Tsai, V. Shanmugam, K. Sardar, Cheng-Liang Huang, and Chen-Sheng Yeh* “Escape from the destruction of the galvanic replacement reaction for solid → hollow → solid conversion process in one pot reaction” Nanoscale. 5, 3863-3871(2013)
39. Shan-Wei Lee ,Jui-Chang Chen*,Cheng-Liang Huang* “Effect of Temperature on the Growth of Silver Nanoparticles Using Plasmon-Mediated Method under the Irradiation of Green LEDs” Materials. 7, 7781-7798 (2014)
40. Chun-Chen Yang, Cheng-Liang Huang (黃正良), Ta-Chih Cheng, Hong-Thih Lai “Inhibitory effect of salinity on the photocatalytic degradation of three sulfonamide antibiotics” International Biodeterioration Biodegradation. 0, 1-10 (2015)
41. Yen-Ling Kuo, Tzong-Yuan Juang,..., Cheng-Liang Huang “Influence of Temperature on the Formation of Silver Nanoparticles by using a Seed‐Free Photochemical Method under Sodium‐Lamp Irradiation” ChemPhysChem. 16, 3254-3263 (2015)
42. Hsiang-Lin Hsu, Tzong-Yuan Juang , Chih-Ping Chen,..., Cheng-Liang Huang, Ru-Jong Jeng “Enhanced efficiency of organic and perovskite photovoltaics from shape-dependent broadband plasmonic effects of silver nanoplates” Solar Energy Materials and Solar Cells. 140, 224-231(2015)
七、 研討會論文
- “Laser Induced Phosphorescence Spectra of Jet-Cooled SO2 between 362 and 384 nm”, Modern Trends in Chemical Dynamics, 8-12 December, 1996. Academia Sinica, Taipei , Taiwan ROC.
- “The state-resolved dynamics study of S 1 acetaldehyde near the dissociation threshold for formation radical products” XVII th Conference on the Dynamics of Molecular Collisions, July 18-23, 1999. PA, U. S.
- “State-resolved dissociation dynamics of triplet acetaldehyde near the dissociation threshold to form CH 3 + HCO” VIII th ACC, N ovember 18-21, 1999 Taipei , Taiwan
- “ Photoisomerization and Photodissociation of Aniline and 4-Methylpyridine “ Tseng, Chien-Ming; Dyakov, Yuri A.; Huang, Cheng-Liang; Mebel, Alexander M.; Lin, Sheng Hsien; Lee, Yuan T.; Ni, Chi-Kung. 27 th International Symposium on Free Radicals July 25-30, 2004, Grand Hotel, Teipei , Taiwan
- “ Electronic Spectra of Molecules with Two C3v Internal Rotors: Torsional Analysis of the A 1 Au – X 1 Ag LIF pectrum of Biacetyl” Huang, Cheng-Liang; Liu, Chen-Lin; Ni, Chi-Kung; Hougen, Jon T. 27 th International Symposium on Free Radicals July 25-30, 2004, Grand Hotel, Teipei, Taiwan
- “ Rotationally Resolved Spectra of Transitions Involving Motion of the Methyl Group of Acetaldehyde in the System A 1 A " – 1 X ~ A'” Chou, Yung-Ching; Huang, Cheng-Liang; Ni, Chi-Kung; Kung, A. H.; Hougen,Jon T.; Chen, I-Chia . 27 th International Symposium on Free Radicals July 25-30, 2004, Grand Hotel, Teipei , Taiwan
八、研究計畫:
九、其他:
技術報告 ( 專題演講 )
年 度 |
計 畫 名 稱 |
補助機關 |
92 │ 93 |
具有分子內轉動振動中型分子之雷射誘發螢光光譜以及能量解析動態學研究 |
國 科 會 |
94 |
ara-hydrogen 間質中 biacetyl 之光譜及分子內轉動振動模位能曲面之研究 立 (2/3) |
國 科 會 |
十、教授課目:
物理化學一 ( 熱力學 ) 、物理化學二 ( 動力學及統計熱力學 ) 、量化導論、高等物化、化學數學、物理化學實驗、普通化學、普通化學實驗